N-甲基二乙醇胺陰離子報(bào)告

Printing time: Wed Sep 29 12:40:04 2010

Injection time: Wed Sep 29 11:37:55 2010

operator: （temporary）, system administrator

分析條件： 儀 器：cic-200     流速：1.0ml/min     量程：1

          分離柱：sh-ac      流動(dòng)相： 碳酸鈉    檢測(cè)方式：抑制電導(dǎo)

數(shù)據(jù)僅供參考，不做判定依據(jù)，采用外標(biāo)法單點(diǎn)校正。

標(biāo)準(zhǔn)品譜圖：

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Rank   Time     Name     Quantity   Area        

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1      4.475    COOH     2          1135007     

2      5.268    CL       2          2095252     

3      7.928    NO3      2          1022979     

4      13.107   H2PO4    5          1239713     

5      15.043   SO4      3          1908172     

6      16.782   OXALIC   2          10855890    

7      21.006   S2O3     2          13394106    

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Total                    18         31651119    

1#樣品譜圖：

樣品稀釋2500倍過0.22微米濾膜，進(jìn)樣計(jì)算。

File opened: E:\\ÕŽõ÷\\2010\\¶þÒÒ´¼°·\\1# 2500 （20100929 11;37;55）.hw

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Rank   Time     Name     Quantity   Area        

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1      4.382    COOH     0          0           

2      5.438    CL       36.21      15863       

3      7.724    NO3      0          0           

4      13.488   H2PO4    1.167e+004 1157335     

5      14.568   SO4      0          0           

6      16.401   oxalic   0          0           

7      20.362   s2o3     0          0           

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Total                    1.171e+004 1173198     

3#樣品譜圖：

樣品稀釋1000倍過0.22微米濾膜，進(jìn)樣計(jì)算

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Rank   Time     Name     Quantity   Area        

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1      4.604    COOH     86.3       48973       

2      5.442    CL       135.6      142021      

3      7.982    NO3      0          0           

4      13.545   H2PO4    2913       722205      

5      15.523   SO4      207.4      131902      

6      17.407   OXALIC   8.695      47199       

7      21.831   S2O3     22.7       152014      

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Total                    3374       1244314     

5#樣品譜圖：（樹脂處理）

樣品稀釋50倍，過陽離子交換樹脂，過0.22微米濾膜，進(jìn)樣計(jì)算

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Rank   Time     Name     Quantity   Area        

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1      4.517    COOH     20.49      232579      

2      5.323    CL       7.445      155995      

3      7.982    NO3      0.9533     9752        

4      13.287   H2PO4    3.711      18401       

5      15.203   SO4      4.314      54877       

6      0.000    OXALIC   0          0           

7      0.000    S2O3     0          0           

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Total                    36.91      471604      

5#樣品譜圖：

樣品稀釋50倍，過0.22微米濾膜，進(jìn)樣計(jì)算

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Rank   Time     Name     Quantity   Area        

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1      4.563    COOH     23.46      266259      

2      5.365    CL       1.575      33005       

3      7.982    NO3      0          0           

4      13.381   H2PO4    2.479      12293       

5      15.356   SO4      1.63       20731       

6      17.407   OXALIC   0          0           

7      21.831   S2O3     0          0           

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Total                    29.14      332288      

2#樣品譜圖：（稀釋10倍）

樣品稀釋10倍，過0.22微米濾膜，進(jìn)樣計(jì)算

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Rank   Time     Name     Quantity   Area        

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2      4.419    COOH     6.608      3283        

3      5.173    CL       640.7      701710      

6      7.785    NO3      未計(jì)算          99010       

7      12.916   H2PO4    未計(jì)算          3021572     

8      14.780   SO4      212.8      240990      

9      16.492   oxalic   6.543      35937       

10     20.362   s2o3     0          0           

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Total                    866.7      4102502     

4#樣品譜圖：（稀釋10倍）

樣品稀釋10倍，過0.22微米濾膜，進(jìn)樣計(jì)算

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Rank   Time     Name     Area%      Area        

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1      4.370    COOH     632.2      46206       

2      5.172    CL       1.523e+004 1113462     

3      7.787    NO3      1219       89098       

4      12.897   H2PO4    2.35e+004  1716794     

5      14.791   SO4      7025       513479      

6      16.503   oxalic   1457       106517      

7      20.769   s2o3     939.7      68681       

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Total                    50003      3654237     

6#樣品譜圖：（稀釋10倍）

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Rank   Time     Name     Area%      Area        

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1      4.418    COOH     0.09465    1593        

2      5.178    CL       68.65      1155244     

3      7.803    NO3      5.423      91276       

4      12.861   H2PO4    9.984      168035      

5      14.774   SO4      15.17      255255      

6      16.559   oxalic   0.683      11495       

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Total                    100        1682898     

1#樣品磷酸二氫根加標(biāo)

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Rank   Time     Name    Area%      Area        

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1     13.568   H2PO4   41.58      9680883     

2     15.421   SO4     1.885      438757      

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Total                   100        23279894